Journal of the Chemical Society (Resumed)

897. Lipids. Part VII. Synthesis of 8-hydroxyoctadec-cis-11-and-trans-11-en-9-ynoic acid: the status of natural 8-hydroxyximenynic acid

L Crombie, BP Griffin

Index: Crombie; Griffin Journal of the Chemical Society, 1958 , p. 4435,4443

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Citation Number: 14

Abstract

For the synthesis of 8-hydroxyximenynic acid the annexed route was followed, but first the reaction was tested on a simpler example, the synthesis of 6-hydroxydodec-7-ynoic acid. A solution of hex-1-ynylsilver in carbon tetrachloride was heated under reflux with 5-

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