New route to. gamma.-ketoaldehydes. Application to the synthesis of cis-jasmone

K Oshima, H Yamamoto, H Nozaki

Index: Oshima,K. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 4446 - 4447

Full Text: HTML

Citation Number: 75

Abstract

The efficiency and generality of the reaction coupled with the ready availability of the starting materials render it very useful in the preparation of heterocycles containing the-N= CHQ- unit. A typical experimental procedure is illustrated by the reaction of yaminopropanol with tert-butyl isocyanide in the presence of silver cyanide leading to the formation of 5, 6-dihydro- 4H-1, 3-oxazine. A mixture of 1.5 g (20 mmol) of y-aminopropanol, 1.7 g (20 mmol) of ...

Related Articles:

Synthesis of 2-alkyl-2-cyclopenten-1-ones. A versatile kinetic alkylation-ozonolysis procedure for the preparation of γ-ketoaldehydes

[Geraghty, Niall W. A.; Morris, Noreen M. Synthesis, 1989 , # 8 p. 603 - 607]

Synthesis of 2-alkyl-2-cyclopenten-1-ones. A versatile kinetic alkylation-ozonolysis procedure for the preparation of γ-ketoaldehydes

[Geraghty, Niall W. A.; Morris, Noreen M. Synthesis, 1989 , # 8 p. 603 - 607]

Convenient synthesis of jasmonoid compounds from. gamma.-(trimethylsiloxy) butyronitrile

[Matsuda, Isamu; Murata, Shizuaki; Izumi, Yusuke Journal of Organic Chemistry, 1980 , vol. 45, # 2 p. 237 - 240]

Synthesis of 2-alkyl-2-cyclopenten-1-ones. A versatile kinetic alkylation-ozonolysis procedure for the preparation of γ-ketoaldehydes

[Geraghty, Niall W. A.; Morris, Noreen M. Synthesis, 1989 , # 8 p. 603 - 607]

2-(2-Nitroethyl)-1, 3-dioxolane as reagent for 3-oxopropyl anion synthon: a new route to jasmonoid and prostaglandin intermediates

[Rosini, Goffredo; Ballini, Roberto; Petrini, Marino; Sorrenti, Pietro Tetrahedron, 1984 , vol. 40, # 19 p. 3809 - 3814]

More Articles...