The Hydrolysis of Disubstituted Alkyl Phosphorochloridates and N, N, N', N'-Tetra-stibstituted Phosphorodiamidic Chlorides in Water and Deuterium Oxide: Heat …

ECF Ko, RE Robertson

Index: Ko,E.C.F.; Robertson,R.E. Canadian Journal of Chemistry, 1973 , vol. 51, p. 597 - 603

Full Text: HTML

Citation Number: 5

Abstract

The pseudo-thermodynamic parameters, Δ H≠, Δ S≠, and Δ C p≠ and the kinetic solvent isotope effects have been determined for the three alkyl-phosphorochloridates, where the alkyl group is ethylisopropyl and n-propyl; for tetra-methyl and tetra-ethyl phosphorodiamidic chlorides; the di-n-propyl and di-isopropyl analog, the di (isopropylmethylcarbinyl) phosphorochloridate and the tetra-ethylthiophosphorodiamidic chloride. These ...