Thermal reactions of organyl chalcogenides with α, β-unsaturated aldehydes

…, NA Korchevin, TA Shilkina, EN Sukhomazova…

Index: Deryagina, E. N.; Korchevin, N. A.; Shilkina, T. A.; Sukhomazova, E. N.; Levanova, E. P. Russian Chemical Bulletin, 1998 , vol. 47, # 3 p. 447 - 450 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1998 , # 3 p. 463 - 466

Full Text: HTML

Citation Number: 1

Abstract

Abstract Thermal gas-phase reactions of acrolein, cinnamaldehyde, and benzaldehyde with diorganyl chalcogenides and diorganyl dichalcogenides were studied. Acrolein does not react with chalcogenides at 300–600° C but completely decomposes under reaction conditions. At 600–650° C, cinnamaldehyde reacts only with diorganyl selenides and diselenides to give benzoselenophene. Its highest yield (53%) is achieved in the reaction ...

Related Articles:

A novel and highly efficient synthetic route to unsymmetrical organoselenides using cesium bases

[Cohen, Richard J.; Fox, Daniel L.; Salvatore, Ralph Nicholas Journal of Organic Chemistry, 2004 , vol. 69, # 12 p. 4265 - 4268]

Nucleophilic cleavage of lactones and esters with zinc selenolates prepared from diselenides in the presence of Zn/AlCl 3

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selenolates prepared from diselenides in the presence of Zn/AlCl 3

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selenolates prepared from diselenides in the presence of Zn/AlCl 3

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selenolates prepared from diselenides in the presence of Zn/AlCl 3

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

More Articles...