The Journal of Organic Chemistry

Electrolytic reactions of fluoro organic compounds. 12. Electrochemical functionalization of chalcogeno compounds. Regioselective anodic acetoxylation of selenides …

K Surowiec, T Fuchigami

Index: Surowiec, Kazimierz; Fuchigami, Toshio Journal of Organic Chemistry, 1992 , vol. 57, # 21 p. 5781 - 5783

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Abstract

Although a-functionalization of amines and arenes is well-established, such functionalization of chalcogeno compounds has been limited and undeve10ped. Z~ For example, it is known that anodic acetoxylation of sulfides takes place only when the concentration of both a substrate and a supporting electrolyte, acetate ions, is extremely high? From a synthetic viewpoint, this is not 80 practical, particularly on a large scale.

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