Organic letters

Effect of the α-Methyl Substituent on Chemoselectivity in Esterase-Catalyzed Hydrolysis of S-Acetyl Sulfanylalkanoates

I Kumar, RS Jolly

Index: Organic Letters, , vol. 1, # 2 p. 207 - 209

Full Text: HTML

Citation Number: 6

Abstract

... Organic Letters. Advanced Search. ... (i) The esterase has a preference for the S enantiomer for both thiol ester and oxoester as is evident in the enantiomeric excess of the products obtained, when the reaction was stopped at 30% conversion (entry 1 in Table 2). (ii) Racemic ...

Related Articles:

Biosynthesis of sulfur compounds. Investigations of the biosynthesis of asparagusic acid

[Parry, Ronald J.; Mizusawa, A.E.; Chiu, I.C.; Naidu, M.V.; Ricciardone, M. Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2512 - 2521]

Lipase-catalyzed stereoselective thiotransesterification of mercapto esters

[Journal of Organic Chemistry, , vol. 55, # 21 p. 5657 - 5659]

Lipase-catalyzed stereoselective thiotransesterification of mercapto esters

[Bianchi, Daniele; Cesti, Pietro Journal of Organic Chemistry, 1990 , vol. 55, # 21 p. 5657 - 5659]

More Articles...