Optimisation of alkene epoxidation catalysed by polymer supported Mo (VI) complexes and application of artificial neural network for the prediction of catalytic …

ML Mohammed, D Patel, R Mbeleck, D Niyogi…

Index: Mohammed, Misbahu Ladan; Patel, Dipesh; Mbeleck, Rene; Niyogi, Debdarsan; Sherrington, David C.; Saha, Basudeb Applied Catalysis A: General, 2013 , vol. 466, p. 142 - 152

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Citation Number: 13

Abstract

Abstract A greener and efficient alkene epoxidation process using heterogeneous molybdenum (Mo) based catalysts and tert-butyl hydroperoxide (TBHP) as an oxidant has been developed. A polybenzimidazole supported Mo (VI) complex, ie PBI. Mo and polystyrene 2-(aminomethyl) pyridine supported Mo (VI) complex, ie Ps. AMP. Mo catalysts have been successfully prepared and characterised. The catalytic activities of the polymer ...

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