Preparation of 2-methylenebenzocyclobutenone by the flash vacuum pyrolysis of 3-[(benzoyloxy) methyl] benzofuran

WS Trahanovsky, AN Amah…

Index: Trahanovsky,W.S.; Amah,A.N.; Cassady,T.J. Journal of the American Chemical Society, 1984 , vol. 106, p. 2696

Full Text: HTML

Citation Number: 6

Abstract

2 3 (35%) stituted methylenecyclobutenones have been prepared by this route, 4 but this route cannot be used to prepare 1. The precursor of 1 would have to be an isobenzofuran which would be too reactive to be pyrolyzed under FVP conditions. In this communication we report the synthesis of 1 by a route involving the FVP of 3 4 (benzoy1oxy) methyl) benzofuran (4).

Related Articles:

6-Endo Heck Cyclization of 3-(2-Iodophenoxy) methylbenzofurans: A Useful Approach to Pterocarpenes

[Fowler, Katherine J.; Ellis, Jillian L.; Morrow, Gary W. Synthetic Communications, 2013 , vol. 43, # 12 p. 1676 - 1682]

Design, synthesis, and evaluation of potential inhibitors of brassinin glucosyltransferase, a phytoalexin detoxifying enzyme from Sclerotinia sclerotiorum

[Pedras, M. Soledade C.; Hossain, Mohammad Bioorganic and Medicinal Chemistry, 2007 , vol. 15, # 17 p. 5981 - 5996]

The Interaction of Heteroaryl??Acrylates and Alanines with Phenylalanine Ammonia??Lyase from Parsley

[Paizs, Csaba; Katona, Adrian; Retey, Janos Chemistry - A European Journal, 2006 , vol. 12, # 10 p. 2739 - 2744]

The Interaction of Heteroaryl??Acrylates and Alanines with Phenylalanine Ammonia??Lyase from Parsley

[Paizs, Csaba; Katona, Adrian; Retey, Janos Chemistry - A European Journal, 2006 , vol. 12, # 10 p. 2739 - 2744]

The Interaction of Heteroaryl??Acrylates and Alanines with Phenylalanine Ammonia??Lyase from Parsley

[Paizs, Csaba; Katona, Adrian; Retey, Janos Chemistry - A European Journal, 2006 , vol. 12, # 10 p. 2739 - 2744]

More Articles...