Tetrahedron

Palladium-catalyzed annulation reaction of o-bromobenzaldehydes with carbonyl compounds to produce naphthol and/or naphthalene derivatives

Y Terao, T Satoh, M Miura, M Nomura

Index: Terao, Yoshito; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu Tetrahedron, 2000 , vol. 56, # 10 p. 1315 - 1320

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Citation Number: 34

Abstract

o-Bromobenzaldehydes undergo annulation with 1, 3-diaryl-2-propanones in the presence of a palladium catalyst to give the corresponding 1, 3-diaryl-2-naphthols in fair to good yields. From the reaction of the aldehydes with 2-substituted 2-alkenals are formed 2, 4- disubstituted 1-naphthols and/or 1, 3-disubstituted naphthalenes accompanied by decarbonylation.

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