The oxidation of alcohols in N-oxyl-immobilized silica gel/aqueous NaOCl disperse systems. A prominent access to a column-flow system

H Tanaka, J Chou, M Mine, M Kuroboshi

Index: Tanaka, Hideo; Chou, Jingyu; Mine, Machiko; Kuroboshi, Manabu Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 9 p. 1745 - 1755

Full Text: HTML

Citation Number: 24

Abstract

The oxidation of alcohols was performed successfully in a disperse system with N-oxyl- adsorbed or immobilized silica gel as a disperse phase and aqueous NaOCl as a disperse medium. In the disperse system, the oxidation of sec-alcohols afforded the corresponding ketones, while prim-alcohols were oxidized to aldehydes and/or carboxylic acids depending on their structures and reaction conditions. The N-oxyl-immobilized silica gel was ...

Related Articles:

Linear polystyrene-stabilized Pt nanoparticles for aerobic alcohol oxidation and hydrogen-transfer reduction in aqueous media

[Ohtaka, Atsushi; Kono, Yuki; Inui, Shigeki; Yamamoto, Syusei; Ushiyama, Tomoki; Shimomura, Osamu; Nomura, Ryoki Journal of Molecular Catalysis A: Chemical, 2012 , vol. 360, p. 48 - 53]

Oxidation of benzoins to benzoic acids using sodium hydride under oxygen atmosphere

[Kang, Sunhae; Joo, Cheonik; Kim, Sun Min; Han, Hogyu; Yang, Jung Woon Tetrahedron Letters, 2011 , vol. 52, # 4 p. 502 - 504]

KMnO4-mediated oxidation as a continuous flow process

[Sedelmeier, Joerg; Ley, Steven V.; Baxendale, Ian R.; Baumann, Marcus Organic Letters, 2010 , vol. 12, # 16 p. 3618 - 3621]

Facile and Selective Deallylations of Esters under 'Aqueous' Free-Radical Conditions

[Perchyonok, V. Tamara; Ryan, Sarah J.; Langford, Steven J.; Hearn, Milton T.; Tuck, Kellie L. Synlett, 2008 , # 8 p. 1233 - 1235]

Palladium nanoparticles in polymers: Catalyst for alkene hydrogenation, carbon-carbon cross-coupling reactions, and aerobic alcohol oxidation

[Park, Cheon Min; Kwon, Min Serk; Park, Jaiwook Synthesis, 2006 , # 22 p. 3790 - 3794]

More Articles...