Chemistry–A European Journal

Interaction of Acetonitrile with Olefins and Alcohols in Zeolite H??ZSM??5: In situ Solid??state NMR Characterization of the Reaction Products

AG Stepanov, MV Luzgin

Index: Stepanov, Alexander G.; Luzgin, Mikhail V. Chemistry - A European Journal, 1997 , vol. 3, # 1 p. 47 - 56

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Citation Number: 25

Abstract

Abstract The reaction products and intermediates from the interaction of acetonitrile with olefins (oct-1-ene) or alcohols (tert-butyl alcohol) in zeolite H-ZSM-5 at 296 K have been characterized with 13 C and 15 N solid-state NMR. It has been shown that coadsorption of acetonitrile and olefin on H-ZSM-5 gives rise to the intermediate N-alkylnitrilium cation represents a persistent species inside a zeolite under anhydrous conditions. Upon ...