The oxidation of ketones with a heteropolyacid, H 5 [PMo 10 V 2 O 40] and dioxygen
…, JM Brégeault, J Mercier, J Martin, C Martin…
Index: Ali, Bassam El; Bregeault, Jean-Marie; Mercier, Jacqueline; Martin, Jacques; Martin, Claudine; Convert, Odile Journal of the Chemical Society, Chemical Communications, 1989 , # 13 p. 825 - 826
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Citation Number: 23
Abstract
The oxidative cleavage of ketones has been studied using several precursors' and has found important applications in industrial syntheses.2 Metal-catalysed oxidation of ketones often occurs in acidic3 or basic4 media. These results and others concerning vanadium-based oxidizing systemss-7 have led us to design vanadium(v) catalyst precursors which are highly soluble in organic media. In order to test one of the most powerful precursors, the heteropolyacid ...
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