Chemische Berichte

Nachweis von 4??Homocubyl??Carbenium??Ionen als reaktive Zwischenstufen

I Mergelsberg, H Langhals, C Rüchardt

Index: Mergelsberg, Ingrid; Langhals, Heinz; Ruechardt, Christoph Chemische Berichte, 1983 , vol. 116, # 1 p. 360 - 366

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Citation Number: 14

Abstract

Abstract Bei der Thermolyse von N-(4-Homocubyl)-N-nitrosoacetamid (9) und bei der Solvolyse von 4-Homocubylbromid (5) in Hexafluor-2-propanol entsteht 4- (Hexafluorisopropoxy) homocuban (6) als Hauptprodukt. Dies beweist das Auftrete von 4- Homocubyl-Carbenium-Ionen als Zwischenstufen beider Reaktionen. Die Solvolysegeschwindigkeit von 4-Homocubylbromid bei 120 C in Hexafluor-2-propanol (k ...

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