Justus Liebigs Annalen der Chemie

Eine einfache Synthesemöglichkeit für S??substituierte 2??Thioaldehyde

HJ Bestmann, J Angerer

Index: Bestmann,H.J.; Angerer,J. Justus Liebigs Annalen der Chemie, 1974 , p. 2085 - 2088

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Abstract

Abstract Setzt man Vinylthioäther 4, die sich nach Wittig aus Aldehyden 1 und (Aryl-oder Alkylthiomethylen) triphenylphoranen 2 herstellen lassen, mit Brom um, so entstehen α, β- Dibromthioäther 5, die beim Stehen in wäßrigem Medium in S-substituierte Thioaldehyde 8 übergehen.

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