Photoinduced nitric oxide release from a hindered nitrobenzene derivative by two-photon excitation

K Hishikawa, H Nakagawa, T Furuta…

Index: Hishikawa, Kazuhiro; Nakagawa, Hidehiko; Furuta, Toshiaki; Fukuhara, Kiyoshi; Tsumoto, Hiroki; et al. Journal of the American Chemical Society, 2009 , vol. 131, p. 7488 - 7489

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Citation Number: 49

Abstract

Here, we demonstrated photoinduced NO generation from a 2, 6-dimethylnitrobenzene- based compound (Flu-DNB) via a two-photon excitation (TPE) process. After pulse laser irradiation to a solution of Flu-DNB, oxidation products of NO were observed. This is the first account of a non-nitrosyl-chelated metal ion containing NO donor which can be controlled by the TPE technique.

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