The Journal of Organic Chemistry

Synthesis of allylazo compounds by reactions of aryldiazonium salts with allylsilanes

H Mayr, K Grimm

Index: Mayr, Herbert; Grimm, Klaus Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1057 - 1059

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Abstract

Summary: Aryldiazonium tetrafluoroborates react with allylsilanes to yield allylazo compounds. If the allylic carbon attached to the azo group carries hydrogen, tau- tomerization with formation of hydrazones takes place. ... The coupling of aryldiazonium ions with arylamines and phenols, discovered by Griess in 1858; has been one of the most important reactions in industrial chemistry for more than a century.2 Among the aliphatic C-nucleophiles ...

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