Reversal of Diastereoselectivities in Intra-and Intermolecular Reactions of 2-Adamantanylidenes Primarily Caused by Electron-Donating and Electron-Withdrawing …

W Knoll, MM Bobek, H Kalchhauser…

Index: Organic Letters, , vol. 5, # 16 p. 2943 - 2946

Full Text: HTML

Citation Number: 16

Abstract

... Volume: Page ... Organic Letters. ... Since computations for the trimethylsilyl group were most promising, 4-azi-1-(trimethylsilyl)adamantane (10) was synthesized (Scheme 3). The required 5-(trimethylsilyl)adamantan-2-one (8) was prepared according to the literature ...