Journal of organometallic chemistry

Polygermanes precurseurs d'especes du germanium a coordinance non usuelle

P Riviere, A Castel, J Satgé, D Guyot

Index: Riviere, P.; Castel, A.; Satge, J.; Guyot, D. Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206

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Citation Number: 27

Abstract

Abstract Several thermal or photochemical α-elimination reactions of functional polygermanes lead to germylenes, R 2 Ge. Photolysis of polygermanes, cyclopolygermanes and polygermylmercury compounds and also hydrogen abstraction from various organohydropolygermanes using t-BuO., lead to the formation of polymetallated chains containing one or two germanium-centered radicals.