Tetrahedron

The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes

WB Jennings, CJ Lovely

Index: Jennings, W. Brian; Lovely, Carl J. Tetrahedron, 1991 , vol. 47, # 29 p. 5561 - 5568

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Citation Number: 181

Abstract

The reaction of phosphinic amides or sulphonamides with an aromatic aldehyde in the presence of titanium tetrachloride and triethylamine provides a simple, one-step preparation of N-phosphinoylimines (5a-e) and N-sulphonylimines (7a-g). The extension of this ...

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