Tetrahedron

Electroreductive acylation of aromatic imines with acylimidazoles

N Kise, S Morimoto

Index: Kise, Naoki; Morimoto, Shinji Tetrahedron, 2008 , vol. 64, # 8 p. 1765 - 1771

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Citation Number: 3

Abstract

The intermolecular reductive coupling of aromatic imines with acylimidazoles was effected by electroreduction in the presence of chlorotrimethylsilane and gave α-amino-α-aryl ketones. This method was also effective for the synthesis of α-amino-α-aryl esters using methoxycarbonylimidazole as an electrophile.

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