Formation of 1-deoxy-D-erythro-2, 3-hexodiulose from Amadori compounds

J Beck, F Ledl, T Severin

Index: Beck, Jakob; Ledl, Franz; Severin, Theodor Carbohydrate Research, 1988 , vol. 177, p. 240 - 243

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Citation Number: 62

Abstract

13 R= AC predominantly in acidic solution, leads to 5-hydroxymethylfurfura12. The l-deoxy- 2, 3-hexodiulose 5 has not yet been detected and its formation as an intermediate has only been postulated. Attempts have been made to synthesise 5. Starting with 3, 6-anhydro-4, 5-~- isopropylidene-D-mannitol, Fisher and co-workers4 obtained crystalline l-deoxy-4, 5-O- isopropylidene-o-erythro-2, 3-hexodiulose. After removing the protecting group under ...