1, 5-Diborabicyclo [3.3. 3] undecane; thermolysis of the product from hydroboration of triallylborane with triethylamine–borane

RW Alder, Z Jin

Index: Alder, Roger W.; Jin, Zhao Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 7 p. 657 - 660

Full Text: HTML

Citation Number: 0

Abstract

Attempts to reproduce the reported preparation of 1, 5-diborabicyclo [3.3. 3] undecane 1 through hydroboration of triallylborane with triethylamine–borane, followed by thermolysis, have led to 1, 5-dipropyl-1, 5-diborocane 2 and other products, but the presence of 1 could not be detected by GC–MS. Treatment of triallylborane with monobromoborane, methanolysis and subsequent thermolysis gave 1, 5-dimethoxy-1, 5-diborocane 3 which ...

Related Articles:

The polyhomologation of 1-boraadamantane: Mapping the migration pathways of a propagating macrotricyclic trialkylborane

[Wagner, Carl E.; Kim, Jang-Seob; Shea, Kenneth J. Journal of the American Chemical Society, 2003 , vol. 125, # 40 p. 12179 - 12195]

1, 1-Vinylboration and 1, 1-Ethylboration of Di (alkyn-1-yl) silanes: Synthesis of New Siloles

[Wrackmeyer, Bernd; Tok, Oleg L.; Bhatti, Moazzam H.; Ali, Saqib Collection of Czechoslovak Chemical Communications, 2002 , vol. 67, # 6 p. 822 - 830]

Scope and Post??Transformations for the Borane??Isocyanide Multicomponent Reactions: Concise Access to Structurally Diverse Heterocyclic Compounds

[Kielland, Nicola; Vicente-Garcia, Esther; Reves, Marc; Isambert, Nicolas; Arevalo, Maria Jose; Lavilla, Rodolfo Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3273 - 3284]

NMR study of the exchange reactions between allyltrialkyltin compounds and lewis acids part 1. Exchanges with boron tribromide and trifluoride and titanium …

[Harston, Paul; Wardell, James L.; Marton, Daniele; Tagliavini, Giuseppe; Smith, Peter J. Inorganica Chimica Acta, 1989 , vol. 162, p. 245 - 250]

More Articles...