Preparation and reactivity of allyl N-[(arylsulfonyl) oxy] carbamates, new reagents for electrophilic transfer of an NHalloc group

C Greck, L Bischoff, F Ferreira…

Index: Greck, C.; Bischoff, L.; Ferreira, F.; Genet, J. P. Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 7010 - 7012

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Citation Number: 34

Abstract

Carbon-nitrogen bonds are usually formed by attack of nucleophilic nitrogen on an electrophilic carbon bearing a leaving group, via an SNz-type reaction. Since the discovery of the polarity reversal process by Sheverdina and Kocheskov, l in combination with the development of new metalation procedures, increased attention has been focused on the development of electrophilic reagents for the amination of carbon nucleophiles. 2 This ...

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