Samarium (II) iodide promoted fragmentation and sequential reactions of aromatic 1, 4-diketones

…, K Blann, CW Holzapfel

Index: Bradley; Williams; Blann, Kevin; Holzapfel, Cedric W. Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2834 - 2836

Full Text: HTML

Citation Number: 20

Abstract

Since its introduction by Kagan, 1 samarium (II) iodide has found manifold applications in organic chemistry. This powerful one-electron reductant has been extensively employed in standard reduction reactions, 2 where it shows remarkable selectivity. Carbon-carbon bondforming reactions have been explored in some detail, 2-4 as have carbon-heteroatom bond fragmentation reactions. 2 The facility with which SmI2 may be incorporated into ...

Related Articles:

Methodology for in Situ Protection of Aldehydes and Ketones Using Trimethylsilyl Trifluoromethanesulfonate and Phosphines: Selective Alkylation and Reduction of …

[Yahata, Kenzo; Minami, Masaki; Yoshikawa, Yuki; Watanabe, Kei; Fujioka, Hiromichi Chemical and Pharmaceutical Bulletin, 2013 , vol. 61, # 12 p. 1298 - 1307]

Dialkylaluminum N, O-Dimethylhydroxylamine Complex as a Reagent to Mask Reactive Carbonyl Groups in Situ from Nucleophiles

[Barrios, Francis J.; Zhang, Xuechao; Colby, David A. Organic Letters, 2010 , vol. 12, # 23 p. 5588 - 5591]

Single??parameter versus dual??parameter correlation for radical reactions. Addition of bromine atoms to α??methylstyrenes

[Jiang, Xi-Kui; Liu, Wayne Wei-Zhong; Wu, Shi-Hui Journal of Physical Organic Chemistry, 1994 , vol. 7, p. 96 - 104]

Kinetics and Mechanism of Acid Catalysed Hydration of α-Methylstyrenes

[Pytela, Oldrich; Trlida, Bronislav Collection of Czechoslovak Chemical Communications, 2007 , vol. 72, # 8 p. 1025 - 1036]

More Articles...