Application du systeme Me3SiCl Li THF a la synthese d'acylsilanes, d'alcools, d'aldehydes, d'esters et de nitriles C-silicies

JP Picard, A Ekouya, J Dunogues, N Duffaut…

Index: Picard,J.-P. et al. Journal of Organometallic Chemistry, 1975 , vol. 93, p. 51 - 70

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Citation Number: 29

Abstract

Abstract Synthesis of C-silylated products by silylation of various functional saturated derivatives (aldehydes, nitriles, acid anhydrides and esters), by mens of the Me 3 SiCl Li THF system used at 0–10 C, is described. Most of the products obtained are new. A mechanism explaining the formation of these derivatives is proposed.