Tetrahedron letters

Biscarbamoyl diselenides as new carbamoylating reagents. Lewis acid promoted carbamoylation of aromatic compounds

SI Fujiwara, A Ogawa, N Kambe, I Ryu, N Sonoda

Index: Fujiwara, Shin-Ichi; Ogawa, Akiya; Kambe, Nobuaki; Ryu, Ilhyong; Sonoda, Noboru Tetrahedron Letters, 1988 , vol. 29, # 47 p. 6121 - 6124

Full Text: HTML

Citation Number: 8

Abstract

Abstract The reaction of biscarbamoyl diselenides with aromatic compounds in the presence of Lewis acids resulted in Friedel-Crafts type carbamoylation (Gatterman amide synthesis) to give corresponding aromatic amides in good yields. This methodology was successfully applied to aroylation and benzylation by use of dibenzoyl diselenide and dibenzyl diselenide, respectively.

Related Articles:

Total synthesis of 8-oxypseudopalmatine and 8-oxypseudoberberine via ring-closing metathesis

[Van, Hue Thi My; Yang, Su Hui; Khadka, Daulat Bikram; Kim, Yong-Chul; Cho, Won-Jea Tetrahedron, 2009 , vol. 65, # 49 p. 10142 - 10148]

Synthesis of 12-oxobenzo [c] phenanthridinones and 4-substituted 3-arylisoquinolones via Vilsmeier–Haack reaction

[Khadka, Daulat Bikram; Yang, Su Hui; Cho, Suk Hee; Zhao, Chao; Cho, Won-Jea Tetrahedron, 2012 , vol. 68, # 1 p. 250 - 261]

More Articles...