Electrochemical carboxylation of fluorocontaining imines with preparation of fluorinated N-phenylphenylglycines

…, VE Titov, VN Bondarenko, VD Pokhodenko

Index: Koshechko; Titov; Bondarenko; Pokhodenko Journal of Fluorine Chemistry, 2008 , vol. 129, # 8 p. 701 - 706

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Citation Number: 20

Abstract

A possibility of obtaining fluorine-containing N-phenylphenylglycine derivatives at yields of up to 85% via the electrochemical carboxylation of corresponding benzalanilines was shown. The influence of imine's electron structure, the nature of supporting electrolyte and cathodic material on such processes is examined. It was found, that increasing electron accepting ability of the substituents in benzylidene and aniline fragments of the imine ...