Efficient synthesis of unsaturated 1-monoacyl glycerols for in meso crystallization of membrane proteins
Y Fu, Y Weng, WX Hong, Q Zhang
Index: Fu, Yu; Weng, Yue; Hong, Wen-Xu; Zhang, Qinghai Synlett, 2011 , # 6 p. 809 - 812
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Citation Number: 6
Abstract
For various 1-MAG lipids, a shorthand nomenclature, NT-MAG, was used to denote the carbon numbers for the respective neck and tail of each single alkyl chain separated by the cis-double bond (Figure [¹] ). [4] [5] Accordingly, monoolein is abbreviated 9.9-MAG. Scheme [¹] outlines our new synthetic route to a series of NT-MAG lipids. Briefly, methyl alkynoates were first synthesized from simple starting materials over four steps, followed by a highly stereoselective cis- ...
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