The monomeric metaphosphate anion in negative-ion chemical-ionization mass spectra of phosphotriesters

…, JR Hass, F Ramirez, JF Marecek

Index: Meyerson, Seymour; Harvan, Donald J.; Hass, J. Ronald; Ramirez, Fausto; Marecek, James F. Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 6877 - 6883

Full Text: HTML

Citation Number: 22

Abstract

Abstract: The monomeric metaphosphate anion, PO3-, was first proposed in 1955 as an intermediate in hydrolysis of phosphomonoesters in aqueous solution. But almost a quarter of a century elapsed before its first direct observation, in the negative-ion chemical- ionization (NICI) mass spectra of certain phosphotriesters. To help define the gas-phase reaction paths leading to the formation and subsequent decomposition of PO<, we have ...

Related Articles:

A convenient synthetic route to phosphate esters from phosphites

[Purnanand; Batra, B. S.; Pant, B. P. Tetrahedron Letters, 1989 , vol. 30, # 13 p. 1687 - 1688]

A convenient synthetic route to phosphate esters from phosphites

[Tetrahedron Letters, , vol. 30, # 13 p. 1687 - 1688]

Solvent isotope effects as a probe of general catalysis and solvation in phosphoryl transfer

[Canadian Journal of Chemistry, , vol. 74, # 6 p. 931 - 938]

Solvent isotope effects as a probe of general catalysis and solvation in phosphoryl transfer

[Canadian Journal of Chemistry, , vol. 74, # 6 p. 931 - 938]

Solvent isotope effects as a probe of general catalysis and solvation in phosphoryl transfer

[Canadian Journal of Chemistry, , vol. 74, # 6 p. 931 - 938]

More Articles...