Ru (II)–arene complexes with N-substituted 3, 4-dihydroquinazoline ligands and catalytic activity for transfer hydrogenation reaction

D Mercan, E Çetinkaya, E Şahin

Index: Mercan, Deniz; Cetinkaya, Engin; Sahin, Ertan Inorganica Chimica Acta, 2013 , vol. 400, p. 74 - 81

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Citation Number: 6

Abstract

In this study, N-coordinated 3, 4-dihydroquinazoline ruthenium (II) complexes were synthesized by the cleavage reaction of [RuCl2 (p-cymene)] 2 with N-substituted 3, 4- dihydroquinazolines. In addition, the X-ray crystal structure of 2, 4, 6-trimethylbenzyl substituted 3, 4-dihydroquinazoline Ru (II) complex (1a) is reported. Furthermore, the resulting piano–stool complexes were evaluated as transfer hydrogenation catalysts for ...