Methyllead (IV) Derivatives Stabilized by DAPTSC2–: Synthesis and Structures of New Diorganolead (IV) Complexes

…, J Ellena, MS García??Tasende, F Namor…

Index: Casas, Jose S.; Castellano, Eduardo E.; Ellena, Javier; Garcia-Tasende, Maria S.; Namor, Facundo; Sanchez, Agustin; Sordo, Jose; Vidarte, Maria J. European Journal of Inorganic Chemistry, 2007 , # 23 p. 3742 - 3750

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Citation Number: 4

Abstract

Abstract The reaction of the bis (thiosemicarbazone) of dimethyl pyridine-2, 6-diyl diketone, H 2 DAPTSC, with PbMe 2 (OAc) 2, PbMePh (OAc) 2 or PbPh 2 (OAc) 2 in MeOH afforded the complexes [PbMe 2 (DAPTSC)],[PbMePh (DAPTSC)] or [PbPh 2 (DAPTSC)](in the first two cases together with [Pb (DAPTSC)]). X-ray crystallography of the Pb (IV) complexes showed that the metal has a pentagonal bipyramidal coordination sphere. The N 3, S 2- ...