A Nonaromatic Route to a Paracyclophane: A Study of the 1, 2, 4, 5-Tetramethylenecyclohexane to Tetramethyl [2.2] paracyclophane Conversion

DT Longone, FP Boettcher

Index: Longone,D.T.; Boettcher,F.-P. Journal of the American Chemical Society, 1963 , vol. 85, p. 3436 - 3443

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Citation Number: 15

Abstract

13, I~-tetra1riethyltricyclo [~.~. 2.~'~~ Jlie~~ deca-~,~~, l~~, l2, 13, l~-hesaerie). The latter dimer is derived from 1-methyl-3, 3, 6-triinethyletiecycloiene, presumably ilia t. he isotneric%,~-diiriethyl-pr~-ly! e~ ie The relative reactivities of the isomeric tetraene monomers are examined in niinbasic media. The significantly greater stability of 1, 2,~, 5- tetramethylenecyclohesa11e allows for il convenient preparation of its solutiotis from the ...

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