Reactions of Bicyclo [2.2. 1] hept-5-ene-2, 3-dicarboximides with Aromatic Azides

…, SV Shishkina, OV Shishkin, LI Kas' yan

Index: Tarabara; Kas'yan; Yarovoi; Shishkina; Shishkin Russian Journal of Organic Chemistry, 2004 , vol. 40, # 7 p. 992 - 998

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Citation Number: 8

Abstract

Abstract Reactions of N-substituted bicyclo [2.2. 1] hept-5-ene-endo-2, endo-3- dicarboximides with o-and p-nitrophenyl azides, as well as with p-nitrophenylsulfonyl azide and p-toluenesulfonyl azide, afforded the corresponding substituted dihydrotriazole (from aryl azides) and arylsulfonylaziridine derivatives (from sulfonyl azides). The exo orientation of the nitrogen-containing cyclic fragments (in keeping with the Alder rule) and endo ...