The Journal of Organic Chemistry

Disproportionation of 3, 3-difluorotetrachloropropene. Application of the hard and soft acids and bases principle to organic halogen compounds

DJ Burton, GC Briney

Index: Burton,D.J.; Briney,G.C. Journal of Organic Chemistry, 1970 , vol. 35, p. 3036 - 3045

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Citation Number: 6

Abstract

Product distributions from the reaction of 3, 3-difluorotetrachloropropene (la) at 50" with aluminum chloride and bromide, titanium tetrachloride, and antimony pentachloride were determined. The aluminum and titanium halides were converted to the fluorides by the reaction; the aluminum fluoride so formed was shown to catalyze the disproportionation of la. l-Bromo-1, 2-dichloro-3, 3, 3-trifluoropropene(8) was formed in the reaction with ...

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