A New Stereoselective Synthesis of (±)??Grandisol Based on the Remote Alkylation Protocol

HJ Monteiro, HA Stefani

Index: Monteiro, Hugo J.; Stefani, Helio A. European Journal of Organic Chemistry, 2001 , # 14 p. 2659 - 2663

Full Text: HTML

Citation Number: 4

Abstract

Grandisol [cis-2-(2-isopropenyl-1-methylcyclobutyl)ethanol, (1a)] is the major component of the pheromonal complex of the cotton boll weevil Anthonomus grandis Boheman, which is a very important pest in the cotton fields of the Americas.1 The compound is also released by females of the ambrosia beetle Trypodendron signatum2 and by males of the bark beetles Pityophthorus pityographus,3Pityogenes quadridens and P. calcaratus.4 Grandisol, along with its ...

Related Articles:

Bridgehead reactivity, nucleophilic and radical additions, and lithium aluminum hydride reduction of 1-(arylsulfonyl) bicyclobutanes: General access to substituted, …

[Gaoni, Yehiel; Tomazic, Alenka Journal of Organic Chemistry, 1985 , vol. 50, # 16 p. 2948 - 2957]

γ-and δ-epoxy sulfones. Formation of different ring-sized products upon reaction with CH3MgI or LiN [CH (CH3) 2] 2

[Decesare, John M.; Corbel, Bernard; Durst, Tony; Blount, John F. Canadian Journal of Chemistry, 1981 , vol. 59, p. 1415 - 1424]

γ-and δ-epoxy sulfones. Formation of different ring-sized products upon reaction with CH3MgI or LiN [CH (CH3) 2] 2

[Decesare, John M.; Corbel, Bernard; Durst, Tony; Blount, John F. Canadian Journal of Chemistry, 1981 , vol. 59, p. 1415 - 1424]

More Articles...