… of anionic oxygen versus neutral sulfur donor atoms of methylsulfanyl-or methylsulfinyl-acetato, 2-benzoato and 2-phenolato to the cis-Pt II (PPh 3) 2 and Pt II (dppe) …

…, S Fantasia, M Manassero, A Pasini, M Sansoni

Index: Battan, Laura; Fantasia, Serena; Manassero, Mario; Pasini, Alessandro; Sansoni, Mirella Inorganica Chimica Acta, 2005 , vol. 358, # 3 p. 555 - 564

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Citation Number: 10

Abstract

The interaction of an excess of the title ligands L− with the cis-Pt (phos) 2 moieties gives compounds a–bcis-[Pt (LO) 2 (phos) 2](a, phos= P (Ph) 3; b, phos= 1/2 dppe), in which O-is preferred to S-coordination. Such preference is confirmed by the fact that the same products are obtained by reaction of excess of L− with the previously reported a–d complexes [Pt (LO, S)(phos) 2]+,(c, phos= PPh3, d, phos= 1/2 dppe), for which chelate ring opening occurs ...

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