Open Chain Derivatives of d-Mannose

ML Wolfrom, LW Georges

Index: Wolfrom; Georges Journal of the American Chemical Society, 1936 , vol. 58, p. 1781

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Citation Number: 6

Abstract

Application of the controlled hydrolysis, with mercuric chloride and cadmium carbonate, to acetylated sugar mercaptals' having the cis-configuration on carbon atoms two and three, such as mannose, rhamnose and a-glucoheptose, has led to impure sirupy products instead of the desired crystalline aldehydo-sugar acetates. The new synthesis of aldehyde-sugar acetates reported from this Laboratory2 offered a different method of approach which has ...