Tetrahedron: Asymmetry

Evaluating dynamic kinetic resolution strategies in the asymmetric hydrosilylation of cyclic ketimines

S Jones, P Zhao

Index: Jones, Simon; Zhao, Peichao Tetrahedron Asymmetry, 2014 , vol. 25, # 3 p. 238 - 244

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Citation Number: 3

Abstract

Abstract Attempts at performing dynamic kinetic resolution on a series of cyclic ketimines by making use of an asymmetric organocatalysed hydrosilylation gave modest conversion and moderate to good enantioselectivities. In the case of α-tetralone derivatives, the use of an N- benzyl protecting group was found to be crucial in obtaining enhanced levels of selectivity.

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