The Journal of Organic Chemistry

Kinetics of thermal and hydrolytic decomposition of 1, 3, 4-dioxazol-2-one derivatives

S Mitra, CG Overberger

Index: Mitra, Smarajit; Overberger, C.G. Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2674 - 2677

Full Text: HTML

Citation Number: 1

Abstract

The synthesis of model compounds 6 and 6 for the homopolymers of vinyl-and isopropenydioxazol-% ones is described. These compounds are hydrolyzed to hydroxamic acids which can be estimated colorimetrically by complexation with Fe3+. The hydrolylitic rates have been determined and the thermolysis rates were followed by measuring undecomposed dioxazolones by the colorimetric method. The isopropyldioxazolone was ...

Related Articles:

Palladium??Catalyzed Amidation by Chemoselective C (sp3) H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor

[Tsukano, Chihiro; Okuno, Masataka; Takemoto, Yoshiji Angewandte Chemie - International Edition, 2012 , vol. 51, # 11 p. 2763 - 2766]

Carbonyldiimidazole-mediated Lossen rearrangement

[Dube, Pascal; Fine Nathel, Noah F.; Vetelino, Michael; Couturier, Michel; Aboussafy, Claude Larrivee; Pichette, Simon; Jorgensen, Matthew L.; Hardink, Mark Organic Letters, 2009 , vol. 11, # 24 p. 5622 - 5625]

Regioselective introduction of heteroatoms at the C-8 position of quinoline N-oxides: remote C–H activation using N-oxide as a stepping stone

[Kang, Taek; Kim, Youngchan; Lee, Donggun; Wang, Zhen; Chang, Sukbok Journal of the American Chemical Society, 2014 , vol. 136, # 11 p. 4141 - 4144]

More Articles...