Tetrahedron

Regioselectivity in the intramolecular allyl transfer reaction catalysed by electrogenerated nickel complexes: influence of metal ions

D Franco, E Duñach

Index: Franco, Delphine; Dunach, Elisabet Tetrahedron, 2002 , vol. 58, # 45 p. 9289 - 9296

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Citation Number: 3

Abstract

The intramolecular transfer of allyl moieties from substituted allyl aryl ethers to carbonyl groups has been studied by electrosynthesis, in a nickel-catalysed reaction. The influence of metal ions such as Mg2+, Zn2+ and Al3+ has been examined. Regioselectivity towards the branched isomer was better with Zn2+ than with Mg2+ ions, but it was higher in the absence of added metal ions.

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