Synthesis and structure of novel closo-dodecaborate-based glycerols

…, I Godovikov, Z Starikova, V Bregadze, D Gabel

Index: Semioshkin, Andrey; Laskova, Julia; Zhidkova, Olga; Godovikov, Ivan; Starikova, Zoya; Bregadze, Vladimir; Gabel, Detlef Journal of Organometallic Chemistry, 2010 , vol. 695, # 3 p. 370 - 374

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Citation Number: 6

Abstract

The reactions of oxonium derivatives of [B12H12] 2− with different glycerol-based nucleophiles were studied. A series of novel closo-dodecaborate-based glycerols with different net charges on the molecules were prepared. A structure of {2-[2-(4-(2, 3- dihydroxypropyl)-dipiperazinium-1-yl)-ethoxy]-ethoxy}-undecahydro-closo-dodecaborate was determined and the existence of different intermolecular H-bonds was shown.