Incorporation of CO 2 in Butadiene Dimerization Catalyzed by Palladium Complexes. Formation of 2-Ethylidene-5-hepten-4-olide

Y Inoue, Y Sasaki, H Hashimoto

Index: Inoue,Y. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 2375 - 2378

Full Text: HTML

Citation Number: 62

Abstract

Reaction of carbon dioxide with butadiene catalyzed by palladium–phosphine complexes was studied. When the reaction was carried out in certain polar, aprotic solvents, such as dimethylformamide (DMF), 2-ethylidene-5-hepten-4-olide was formed in about 5% yield by the incorporation of CO 2 together with the formation of butadiene linear dimers. The main dimer was 1, 3, 7-octatriene. The ditertiary phosphines, R 2 PCH 2 CH 2 CH 2 PR 2 where ...

Related Articles:

. alpha.-Haloalkanesulfonyl bromides in organic synthesis. 5. Versatile reagents for the synthesis of conjugated polyenes, enones, and 1, 3-oxathiole 1, 1-dioxides

[Block,E.; Aslam,M.; Eswarakrishnan,V. Journal of the American Chemical Society, 1986 , vol. 108, p. 4568]

Selective telomerization of butadiene with various nucleophiles catalyzed by polymer-bound palladium (0) complexes

[Kaneda, Kiyotomi; Kurosaki, Hiroo; Terasawa, Masami; Imanaka, Toshinobu; Teranishi, Shiichiro Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2356 - 2362]

Selective telomerization of butadiene with various nucleophiles catalyzed by polymer-bound palladium (0) complexes

[Kaneda, Kiyotomi; Kurosaki, Hiroo; Terasawa, Masami; Imanaka, Toshinobu; Teranishi, Shiichiro Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2356 - 2362]

Highly selective biphasic telomerization of butadiene with glycols: scope and limitations

[Behr, Arno; Urschey, Michael Advanced Synthesis and Catalysis, 2003 , vol. 345, # 11 p. 1242 - 1246]

Selective telomerization of butadiene with various nucleophiles catalyzed by polymer-bound palladium (0) complexes

[Kaneda, Kiyotomi; Kurosaki, Hiroo; Terasawa, Masami; Imanaka, Toshinobu; Teranishi, Shiichiro Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2356 - 2362]

More Articles...