Iridium??Catalyzed H/D Exchange

J Krüger, B Manmontri, G Fels

Index: Krueger, Jens; Manmontri, Boripont; Fels, Gregor European Journal of Organic Chemistry, 2005 , # 7 p. 1402 - 1408

Full Text: HTML

Citation Number: 12

Abstract

Abstract The scope and limitation of an iridium-catalysed H/D exchange reaction has been investigated. Our results suggest a general mechanism for specific labelling at aromatic and non-aromatic double bonds by D 2 O if an electron-donating group is in a 1, 4-relation with the carbon where the H/D exchange takes place.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)