Compact Metal–Organic Frameworks for Anti??Corrosion Applications: New Binary Linear Saturated Carboxylates of Zinc

…, E Rocca, M François, J Steinmetz

Index: Mesbah, Adel; Jacques, Sophie; Rocca, Emmanuel; Francois, Michel; Steinmetz, Jean European Journal of Inorganic Chemistry, 2011 , # 8 p. 1315 - 1321

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Citation Number: 3

Abstract

Abstract Zinc-based metal–organic frameworks (MOFs), binary zinc carboxylates ZnC n C n′ with C n and C n′= CH 3 (CH 2) n–2 COO–, have been synthesised and characterised for anti-corrosion applications. The crystallographic structures of ZnC 10 C 14 and ZnC 10 C 16 were determied from synchrotron powder diffraction data and refined by the Rietveld method. Protective coatings on electrogalvanised steel composed of ZnC 12 C 16 have ...