Dalton Transactions

A chiral mixed metal–organic framework based on a Ni (saldpen) metalloligand: synthesis, characterization and catalytic performances

Y Ren, X Cheng, S Yang, C Qi, H Jiang, Q Mao

Index: Ren, Yanwei; Cheng, Xiaofei; Yang, Shaorong; Qi, Chaorong; Jiang, Huanfeng; Mao, Qiuping Dalton Transactions, 2013 , vol. 42, # 27 p. 9930 - 9937

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Citation Number: 33

Abstract

A three-dimensional (3D) chiral mixed metal–organic framework [Cd 4 Cl (Ni–L) 3 (Ni–HL)(H 2 O) 6 (DMF)]· 4DMF (CMOF 1) based on a new enantiopure dicarboxyl-functionalized Ni (saldpen) metalloligand Ni–H 2 L and a novel tetranuclear cadmium cluster [Cd 4 Cl (CO 2) 7 (CO 2 H)] has been synthesized and characterized by elemental analyses, IR and UV-vis spectra, thermogravimetric analysis, nitrogen and carbon dioxide adsorption, powder and ...

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