New synthesis of olefins

N Kornblum, SD Boyd, HW Pinnick…

Index: Kornblum,N. et al. Journal of the American Chemical Society, 1971 , vol. 93, p. 4316 - 4318

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Citation Number: 47

Abstract

I number of effective methods for converting aliphatic, and alicyclic, nitro compounds into vicinal dinitro compounds, I, are known; 2-4 the reaction originally described by Seigle, Hass, and Hudgin2 has proved to be especially useful. When a nitroparaffin salt is treated with bromine in the cold it is rapidly and quantitatively converted to the a-bromonitro compound; this, without being purified, is treated with a second equivalent of the ...

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