Synthesis and Application of a Permanently Immobilized Olefin??Metathesis Catalyst

SC Schürer, S Gessler, N Buschmann…

Index: Schuerer, Stephan C.; Gessler, Simon; Buschmann, Nicole; Blechert, Siegfried Angewandte Chemie - International Edition, 2000 , vol. 39, # 21 p. 3898 - 3901

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Citation Number: 201

Abstract

Abstract Immobilized on Merrifield polystyrene, catalyst 1 shows high activity and stability in different types of olefin metathesis. The products can be isolated in high purity by simple filtration, while the immobilized catalyst 1 can be recycled and used up to four times in the ring-closing metathesis of 2. Mes= methane sulfonate, Ts= toluene sulfonate, Cy= cyclohexyl.

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