Tetrahedron

Rhodium-catalysed hydroformylation and carbonylation of N-alkenyl-1, 3-diaminopropanes

DJ Bergmann, EM Campi, WR Jackson, QJ McCubbin…

Index: Bergmann, David J.; Campi, Eva M.; Jackson, W. Roy; McCubbin, Quentin J.; Patti, Antonio F. Tetrahedron, 1997 , vol. 53, # 51 p. 17449 - 17460

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Citation Number: 13

Abstract

The rhodium catalysed reactions of N-alkenyl-1, 3-diaminopropanes with H 2CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo-and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H2 and CO in the gas mixture and in some cases formation of a single compound can be achieved.

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