Tetrahedron

Use of a bulky phosphine of weak σ-donicity with palladium as a versatile and highly-active catalytic system: allylation and arylation coupling reactions at 10− 1–10− 4 …

…, A Fihri, R Amardeil, P Meunier, H Doucet, M Santelli

Index: Hierso, Jean-Cyrille; Fihri, Aziz; Amardeil, Regine; Meunier, Philippe; Doucet, Henri; Santelli, Maurice Tetrahedron, 2005 , vol. 61, # 41 p. 9759 - 9766

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Citation Number: 57

Abstract

Carbon–carbon (sp2–sp2 and sp1–sp2) and carbon–nitrogen (nucleophilic allylation) coupling processes are promoted by a catalytic system containing [PdCl (η3–C3H5)] 2 with the new ferrocenyl bis (difurylphosphine) 1, 1′-bis [di (5-methyl-2-furyl) phosphino] ferrocene, Fc [P (FuMe) 2] 2. Starting from aryl bromides or allylic acetates this versatile catalyst system may be used at low palladium loadings (10− 1–10− 4mol%) in some Heck, ...

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