Synthetic communications

Radical Chemistry Based on (+)-cis-Pinononic and (+)-CIS-Pinonic Acids

DHR Barton, G Fontana

Index: Barton, Derek H. R.; Fontana, Giovanni Synthetic Communications, 1996 , vol. 26, # 10 p. 1953 - 1968

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Citation Number: 11

Abstract

Abstract A high yield method for the preparation of (+)-cis-pinononic acid starting from the inexpensive (+)-α-pinene has been developed. The capture of the cyclobutyl radical from decarboxylation of (+)-cis-pinononic acid has been investigated. Moreover the radical decarboxylation of (+)-cis-pinonic acid to the corresponding nor-alkane was studied.

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